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Title: | Methylene Blue Sensitized Photodechlorination of Isomeric Mono- and Dichloroanilines via Molecular Complex Formation Mechanism |
Authors: | Pande, U. C. Dwivedi, Ankur H. |
Keywords: | Chemical Faculty Papers Faculty Papers ITFCH031 Photosensitized Dechlorination Chloroanilines Dichloroanilines Methylene Blue |
Issue Date: | 2011 |
Abstract: | The photosensitized dechlorination of isomeric mono- and dichloroanilines has been studied using methylene blue as photosensitizer in alkaline medium. The dechlorination products have been identified and formation of molecular complex between aniline and methylene blue has been observed. The effects of the pH, concentration of the sensitizer, concentration of the substrate, the intensity of the light and the temperature on the rate of the reaction have been studied. The quantum efficiency of the photodechlorination has been evaluated. The mechanism of the photodechlorination has been suggested. |
Description: | E-Journal of Chemistry, 2011, Vol - 8 (3), Page No. 1086-1093. |
URI: | http://hdl.handle.net/123456789/2714 |
Appears in Collections: | Faculty Papers, Chemical |
Files in This Item:
File | Description | Size | Format | |
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ITFCH031-2.pdf | ITFCH031-2 | 102.43 kB | Adobe PDF | ![]() View/Open |
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