Please use this identifier to cite or link to this item: http://10.1.7.192:80/jspui/handle/123456789/3448
Title: Synthesis and Dissociation of Clix(6)arene Hydroxamic acids
Authors: Agrawal, Y.K.
Kunji, P.S.
Keywords: Calixarene
calixhydroxamic acid
synthesis
ionization constant
Facuty Paper
Pharmacy Faculty Paper
Issue Date: 2005
Publisher: Shiraz University
Series/Report no.: IPFP0082
Abstract: Calix(6)arene hydroxamic acids (III) are synthesised for the first time by reacting calix(6)arene acid chloride(II) with substituted hydroxylamines at low temperature in the presence of sodium bicarbonate. The p-carboxycalix(6)arene(I) is obtained by an acid catalysed condensation reaction of p-hydroxybenzoic acid and formaldehyde. These calixarenes are characterised by melting point, UV, IR, 1H NMR and mass spectra. The thermodynamic ionization constants of calixarene hydroxamic acids have been determined by a pH titration technique in dioxane-water media.
Description: Iranian Journal of Science & Technology, Transaction A, Vol. 29, No. A1
URI: http://10.1.7.181:1900/jspui/123456789/3448
Appears in Collections:Faculty Papers

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